IndiumV3, Main, Repository, bibRecord, 010818

Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films

Identifieur interne : 010818 ( Main/Repository ); précédent : 010817; suivant : 010819

Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films

Auteurs : RBID : Pascal:01-0229181

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Electrochromisme, Couche mince, Indium Oxyde, Zinc Oxyde, Relation structure propriété, Conductivité électrique, Propriété électrochimique, Electrode optiquement transparente, Morphologie, Structure surface, Microscopie électronique transmission, Solvant organique, Carbonate organique, Carbonate(diméthyl), 1,3-Dioxolan-2-one.

English descriptors

KwdEn :
- Electrical conductivity, Electrochemical properties, Electrochromism, Experimental study, Indium Oxides, Morphology, Optically transparent electrode, Organic carbonate, Organic solvent, Property structure relationship, Surface structure, Thin film, Transmission electron microscopy, Zinc Oxides.

Abstract

To optimize the physical properties of In₂O₃-ZnO pulsed laser deposited thin films, we embarked on a systematic study of their microstructural characterization and transport properties. We found that the electrical properties of the films are greatly governed by their microstructure, which evolves from granular to fiber and to columnar textures, as we go from cubic In₂O₃ to hexagonal ZnO via Zn_kIn₂O_k+3 layered structure in the binary In₂O₃ ZnO phase diagram. Maximum conductivity is reached for a Zn/(Zn + In) = 0.5 (at.) composition having a layered Zn_kIn₂O_k+3- type structure with essentially k = 2, which was synthesized for the first time. Electrochemical measurements show that this film can be used as a transparent electrode in electrochromic devices operating either in an aqueous or organic medium.

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Links to Exploration step

Pascal:01-0229181

Le document en format XML

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<author><name sortKey="Dupont, L" uniqKey="Dupont L">L. Dupont</name>
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<author><name sortKey="Marcel, C" uniqKey="Marcel C">C. Marcel</name>
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<author><name sortKey="Laik, B" uniqKey="Laik B">B. Laïk</name>
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<author><name sortKey="Guery, C" uniqKey="Guery C">C. Guery</name>
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<s2>80039 Amiens</s2>
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<author><name sortKey="Tarascon, J M" uniqKey="Tarascon J">J. M. Tarascon</name>
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<s2>80039 Amiens</s2>
<s3>FRA</s3>
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<idno type="stanalyst">PASCAL 01-0229181 INIST</idno>
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<seriesStmt><idno type="ISSN">0013-4686</idno>
<title level="j" type="abbreviated">Electrochim. acta</title>
<title level="j" type="main">Electrochimica acta</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Electrical conductivity</term>
<term>Electrochemical properties</term>
<term>Electrochromism</term>
<term>Experimental study</term>
<term>Indium Oxides</term>
<term>Morphology</term>
<term>Optically transparent electrode</term>
<term>Organic carbonate</term>
<term>Organic solvent</term>
<term>Property structure relationship</term>
<term>Surface structure</term>
<term>Thin film</term>
<term>Transmission electron microscopy</term>
<term>Zinc Oxides</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Electrochromisme</term>
<term>Couche mince</term>
<term>Indium Oxyde</term>
<term>Zinc Oxyde</term>
<term>Relation structure propriété</term>
<term>Conductivité électrique</term>
<term>Propriété électrochimique</term>
<term>Electrode optiquement transparente</term>
<term>Morphologie</term>
<term>Structure surface</term>
<term>Microscopie électronique transmission</term>
<term>Solvant organique</term>
<term>Carbonate organique</term>
<term>Carbonate(diméthyl)</term>
<term>1,3-Dioxolan-2-one</term>
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<front><div type="abstract" xml:lang="en">To optimize the physical properties of In<sub>2</sub>
O<sub>3</sub>
-ZnO pulsed laser deposited thin films, we embarked on a systematic study of their microstructural characterization and transport properties. We found that the electrical properties of the films are greatly governed by their microstructure, which evolves from granular to fiber and to columnar textures, as we go from cubic In<sub>2</sub>
O<sub>3</sub>
 to hexagonal ZnO via Zn<sub>k</sub>
In<sub>2</sub>
O<sub>k+3</sub>
 layered structure in the binary In<sub>2</sub>
O<sub>3</sub>
 ZnO phase diagram. Maximum conductivity is reached for a Zn/(Zn + In) = 0.5 (at.) composition having a layered Zn<sub>k</sub>
In<sub>2</sub>
O<sub>k+3</sub>
- type structure with essentially k = 2, which was synthesized for the first time. Electrochemical measurements show that this film can be used as a transparent electrode in electrochromic devices operating either in an aqueous or organic medium.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films</s1>
</fA08>
<fA09 i1="01" i2="1" l="ENG"><s1>Electrochromics: A selection of papers from the 4th International Meeting on Electrochromism (IME-4), Uppsala, Sweden, 21-23 August 2000</s1>
</fA09>
<fA11 i1="01" i2="1"><s1>NAGHAVI (N.)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>DUPONT (L.)</s1>
</fA11>
<fA11 i1="03" i2="1"><s1>MARCEL (C.)</s1>
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<fA11 i1="04" i2="1"><s1>MAUGY (C.)</s1>
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<fA11 i1="05" i2="1"><s1>LAÏK (B.)</s1>
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<fA11 i1="06" i2="1"><s1>ROUGIER (A.)</s1>
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<fA11 i1="07" i2="1"><s1>GUERY (C.)</s1>
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<fA11 i1="08" i2="1"><s1>TARASCON (J. M.)</s1>
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<fA12 i1="01" i2="1"><s1>AZENS (A.)</s1>
<s9>ed.</s9>
</fA12>
<fA12 i1="02" i2="1"><s1>GRANQVIST (C. G.)</s1>
<s9>ed.</s9>
</fA12>
<fA14 i1="01"><s1>Laboratoire de Réactivité et de Chimie des Solides, Université de Picardie Jules Verne, UPRES A 6007, 33 rue St. Leu</s1>
<s2>80039 Amiens</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
<sZ>8 aut.</sZ>
</fA14>
<fA15 i1="01"><s1>Department of Materials Science, The Ångström Laboratory, Uppsala University, P.O. Box 534</s1>
<s2>75121 Uppsala</s2>
<s3>SWE</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA15>
<fA20><s1>2007-2013</s1>
</fA20>
<fA21><s1>2001</s1>
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<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>To optimize the physical properties of In<sub>2</sub>
O<sub>3</sub>
-ZnO pulsed laser deposited thin films, we embarked on a systematic study of their microstructural characterization and transport properties. We found that the electrical properties of the films are greatly governed by their microstructure, which evolves from granular to fiber and to columnar textures, as we go from cubic In<sub>2</sub>
O<sub>3</sub>
 to hexagonal ZnO via Zn<sub>k</sub>
In<sub>2</sub>
O<sub>k+3</sub>
 layered structure in the binary In<sub>2</sub>
O<sub>3</sub>
 ZnO phase diagram. Maximum conductivity is reached for a Zn/(Zn + In) = 0.5 (at.) composition having a layered Zn<sub>k</sub>
In<sub>2</sub>
O<sub>k+3</sub>
- type structure with essentially k = 2, which was synthesized for the first time. Electrochemical measurements show that this film can be used as a transparent electrode in electrochromic devices operating either in an aqueous or organic medium.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01H08</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Etude expérimentale</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Experimental study</s0>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Estudio experimental</s0>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Electrochromisme</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Electrochromism</s0>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Electrocromismo</s0>
<s5>02</s5>
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<fC03 i1="03" i2="X" l="FRE"><s0>Couche mince</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Thin film</s0>
<s5>04</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Capa fina</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Indium Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Indium Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Indio Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Zinc Oxyde</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Zinc Oxides</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Zinc Óxido</s0>
<s2>NC</s2>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Relation structure propriété</s0>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Property structure relationship</s0>
<s5>09</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Relación estructura propiedad</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Conductivité électrique</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Electrical conductivity</s0>
<s5>10</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Conductividad eléctrica</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Propriété électrochimique</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Electrochemical properties</s0>
<s5>11</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Propiedad electroquímica</s0>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Electrode optiquement transparente</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Optically transparent electrode</s0>
<s5>13</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Electrodo ópticamente transparente</s0>
<s5>13</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Morphologie</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Morphology</s0>
<s5>16</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Morfología</s0>
<s5>16</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Structure surface</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Surface structure</s0>
<s5>17</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Estructura superficie</s0>
<s5>17</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Microscopie électronique transmission</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Transmission electron microscopy</s0>
<s5>18</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Microscopía electrónica transmisión</s0>
<s5>18</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Solvant organique</s0>
<s5>20</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Organic solvent</s0>
<s5>20</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Solvente orgánico</s0>
<s5>20</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Carbonate organique</s0>
<s5>21</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Organic carbonate</s0>
<s5>21</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Carbonato orgánico</s0>
<s5>21</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Carbonate(diméthyl)</s0>
<s1>SOL</s1>
<s2>NK</s2>
<s4>INC</s4>
<s5>62</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>1,3-Dioxolan-2-one</s0>
<s1>SOL</s1>
<s2>NK</s2>
<s4>INC</s4>
<s5>63</s5>
</fC03>
<fN21><s1>155</s1>
</fN21>
</pA>
<pR><fA30 i1="01" i2="1" l="ENG"><s1>IME-4 International Meeting on Electrochromism</s1>
<s2>4</s2>
<s3>Uppsala SWE</s3>
<s4>2000-08-21</s4>
</fA30>
</pR>
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   |texte=   Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films
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Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films

Systematic study and performance optimization of transparent conducting indium-zinc oxides thin films

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